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  • 专利说明
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    • 专利摘要:
    The invention relates to the treatment of mining residues in the form of aqueous effluents comprising solid particles. The method of the invention makes it possible to separate all or part of the water from an aqueous effluent comprising solid particles. This process comprises (a) adding to the effluent at least one sulfonated dispersing agent, and then (b) adding at least one solid particle flocculation agent. The invention also relates to a composition comprising an aqueous effluent comprising dispersed and flocculated solid particles. Preferably, it relates to a composition comprising an aqueous effluent comprising solid particles, at least one sulphonated dispersing agent and at least one solid particles flocculation agent.
    公开号:FR3044655A1
    申请号:FR1561918
    申请日:2015-12-07
    公开日:2017-06-09
    发明作者:Cedrick Favero；Morgan Tizzotti
    申请人:SNF SA；
    IPC主号:
    专利说明:

    PROCESS FOR TREATING AQUEOUS EFFLUENT
    DESCRIPTION The invention relates to the treatment of mining residues in the form of aqueous effluents comprising solid particles. The method of the invention makes it possible to separate all or part of the water from an aqueous effluent comprising solid particles. This process comprises (a) adding to the effluent at least one sulfonated dispersing agent, and then (b) adding at least one solid particle flocculation agent. The invention also relates to a composition comprising an aqueous effluent comprising dispersed and flocculated solid particles. Preferably, it relates to a composition comprising an aqueous effluent comprising solid particles, at least one sulphonated dispersing agent and at least one solid particles flocculation agent.
    Many mining methods produce residues in the form of aqueous effluents comprising solid particles. For example, the production of hydrocarbons from oil sands or oil sands leads to such tailings. For example, tailings management is a major challenge for the mining industry, particularly since the beginning of oil sands mining. Operators are responsible for determining how to dispose of these by-products safely and effectively. The challenge is all the greater because of the size of oil sands operations.
    In general, the mining industry also produces such residues or waste materials, in particular during the extraction of ores for the production of coal, diamond, phosphate or various metals, for example aluminum, platinum, iron, gold, copper, silver, etc. Such residues can also result from the transformation of ores or industrial processes or washing.
    Tailings can take different forms, including sludge. In general, these are suspensions of solid particles in water. Generally, oil sands tailings consist of water, clay, sand and residual hydrocarbons from the extraction process.
    Current industry practices have been to pump tailings into large tailings ponds. Subsequently, the heaviest material, mainly sand, settles to the bottom, while water rises to the surface and can be recycled. The intermediate layer, known as mature fine tailings (MFT), is usually composed of 70% water and 30% fine clay particles. Naturally, the mature fine tailings layer could take centuries to solidify. The continued development of mining has necessitated the creation of a growing number of larger settling ponds.
    For example, mineral sludge produced by physical or chemical sand sands treatment processes is stored in open pits, ponds, dams, or semi-liquid fill. These large volumes of stored mud therefore create a real danger, especially in the event of breakage of dikes.
    Particularly because of technical, environmental or regulatory requirements, it is now necessary to find a way to accelerate or improve the efficiency of the processing of mature fine tailings into a firm deposit that can then be rehabilitated.
    Soil remediation following mining is made mandatory by environmental legislation. Accelerated tailings treatment is also required, including increasing the sedimentation rate of tailings to effectively recycle water and reduce tailings volume.
    Continuous methods of treatment are also needed.
    There is also a need for treatment methods to eliminate or reduce the problems associated with the handling and transport of aqueous effluents, particularly when the treatment of the aqueous effluent is carried out at a place remote from the place where it is produced. . Indeed, it is common that the ore or the bituminous sand at the origin of the aqueous effluent is treated at a place remote from the treatment site of the aqueous effluent. The high viscosity of the aqueous effluent can increase the problems related to the handling or transport of this effluent. This high viscosity also leads to an increase in energy consumption during handling or transport of this effluent. The incorporation of other elements, in particular elements comprising flocculating agents, is also problematic because of the high viscosity of the aqueous fluid to be treated. The mixing times or the amounts of flocculating agent to be integrated can then be increased.
    Moreover, the dilution of the aqueous fluid to lower the viscosity leads to larger amounts of water taken from the surrounding natural environment. Such dilution also results in an increase in the total volume of the aqueous fluids to be treated.
    In general, the separation and recycling of all or part of the water present in the aqueous effluents mining are essential goals during mining. Thus, the aqueous effluent treatment processes comprising solid particles have the essential goal of improving the water separation efficiency, in particular for the purpose of recycling the separated water and to allow easy handling of the final residue. . The increase of this net water release yield (NWR) is an important goal of aqueous effluent treatment processes including solid particles.
    Methods of physical treatment of these mining residues are known, for example centrifugation, filtration, electrophoresis and electrocoagulation. On the other hand, chemical processes emerge. For example, processes involving the addition of chemicals such as sodium silicate, organic flocculants, inorganic coagulants, oxidizing agents, reducing agents or carbon dioxide are known. It is also known to use synthetic or natural polymers such as coagulants or flocculants to separate the solids from the liquid.
    Moreover, dispersants are products known to be able to thin the most concentrated aqueous suspensions to facilitate their transport. However, the use of such dispersants leads to problems in the subsequent use of flocculation agents. Indeed, the addition of flocculants to suspensions comprising dispersants is inefficient; the solid particles present in the suspension are not flocculated. Thus, traditional anionic polyacrylamide flocculants become ineffective when mixed with such dispersed suspensions.
    It is therefore necessary to have a method employing a dispersing agent that does not affect flocculation.
    Thus, even if there are techniques for treating tailings, these techniques do not provide a fully effective solution to the problems encountered, particularly from a technical, environmental or public order point of view.
    It is therefore necessary to have methods that make it possible to provide solutions to all or part of the problems of the methods of the state of the art.
    Thus, the invention provides a method of treating an aqueous effluent comprising solid particles, comprising (a) adding to the effluent at least one sulfonated dispersing agent; and then (b) adding at least one solid particle flocculation agent.
    The treatment method according to the invention therefore comprises (a) the dispersion of the solid particles in the aqueous support by means of the sulphonated dispersing agent; then (b) flocculation of the solid particles dispersed by means of the flocculation agent.
    According to the invention, the effluent is advantageously a mining extraction effluent, preferably an extraction effluent of bituminous sand or oil sand. In addition to the solid particles, the effluent comprises water. It may include sand, clay and water or sand, clay, water and residual bitumen. Generally, the aqueous effluent according to the invention comprises from 5 to 70% by weight, preferably from 20 to 50% by weight, more preferably from 30 to 40% by weight, of solid particles, in particular mineral particles. The effluent treated according to the process of the invention may comprise different residues. These residues may be fresh residues or fine residues. Preferably, it is an effluent comprising mature fine tailings (RFMs or MFTs), in particular an effluent comprising mature fine tailings (RFMs or MFTs) comprising an amount of clays ranging from 5 to 70% by weight.
    In general, the aqueous effluent from oil sands mining treated according to the invention may also comprise residual bitumen. The residual bitumen is then present in a small quantity, generally in an amount of less than 5% by mass of aqueous effluent.
    The process according to the invention comprises the addition to the effluent of at least one sulphonated dispersing agent.
    Preferably, the sulphonated dispersing agent is added in a mass quantity ranging from 10 to 10,000 ppm, preferably from 200 to 5,000 ppm, more preferably from 500 to 2,000 ppm, relative to the amount of effluent. Also preferably, the sulphonated dispersing agent is added in a mass quantity ranging from 10 to 10,000 g, preferably from 200 to 5,000 g, more preferably from 500 to 2,000 g per tonne of effluent.
    Advantageously, the sulfonated dispersing agent makes it possible to fluidize the effluent, in particular to reduce its viscosity, in particular to facilitate its transport. According to the invention, the molecular weight of the sulphonated dispersing agent can vary quite widely, particularly as a function of the effluent to be treated or depending on the sulphonated dispersing agent as such. Generally, the sulfonated dispersing agent has a molecular weight ranging from 1,000 to 50,000 g / mol, preferably from 5,000 to 30,000 g / mol, more preferably from 10,000 to 25,000 g / mol.
    Preferably, the sulphonated dispersing agent is chosen from homo- or copolymers of 2-acrylamido-2-methylpropanesulphonic acid (ATBS or tert-butyl sulphonic acid acylamide), of vinyl sulphonic acid, of styrene sulphonic acid, naphatalenesulphonic acid, allylsulfonic acid or their water-soluble salts. It can also be chosen from co-polymers of 2-acrylamido-2-methylpropanesulphonic acid, vinyl sulfonic acid, styrene sulfonic acid, naphatalenesulphonic acid, allylsulfonic acid or their soluble salts in water and at least one nonionic monomer selected from acrylamide; methacrylamide; N-mono-derivatives of acrylamide; N-mono-derivatives of methacrylamide; Ν, Ν-derivatives of acrylamide; Ν, Ν-derivatives of methacrylamide; acrylic esters; methacrylic esters; N-vinylformamide and N-vinylpyrrolidone.
    The water-soluble salts of these monomers are typically salts of an alkali metal, an alkaline earth metal or ammonium.
    Preferably, the sulphonated dispersing agent may be chosen from poly-2-acrylamido-2-methylpropanesulphonic acid, polyvinyl sulphonic acid, polystyrene sulphonic acid, polynaphthalene sulphonic acid, polyallyl sulphonic acid or their mixtures.
    In a particularly preferred manner, the sulphonated dispersing agent may be chosen from co-polymers prepared from nonionic monomers, preferably used in an amount ranging from 0.01 to 90 mol%.
    In addition to the sulfonated dispersing agent, the process according to the invention uses a flocculating agent. According to the invention, the flocculation of the solid particles present in the aqueous effluent is the physico-chemical process in which the solid particles suspended in the aqueous effluent agglomerate to form flocs. These flocs are larger particles that typically sediment much faster than the primary particles they are formed from.
    In a preferred manner for the process according to the invention, the flocculating agent is added in a quantity by mass ranging from 10 to 10,000 ppm relative to the quantity of solid particles included in the aqueous effluent. From a practical point of view, it is added in an amount ranging from 10 to 10,000 g per ton of solid particles included in the aqueous effluent.
    Also preferably, the flocculation agent has a molecular weight ranging from 3 to 40 million g / mol. Similarly, the molecular weight of the flocculating agent can range from 5 to 30 million g / mol.
    Many compounds can be used as a flocculating agent for the process according to the invention. It can especially be a polymer prepared from at least one nonionic monomer or a polymer prepared from at least one anionic monomer, or even a polymer prepared from at least one a cationic monomer. Preferably, it is a co-polymer prepared from at least one nonionic monomer and from at least one anionic monomer, for example at a molar proportion of at least 70% by weight. a nonionic monomer and 30% of at least one anionic monomer.
    In a preferred manner according to the invention, the flocculation agent is a polymer prepared from at least one nonionic monomer chosen from acrylamide; methacrylamide; N-mono-derivatives of acrylamide; N-mono-derivatives of methacrylamide; Ν, Ν-derivatives of acrylamide; Ν, Ν-derivatives of methacrylamide; acrylic esters; methacrylic esters; N-vinylformamide and N-vinylpyrrolidone. It may be chosen from polymers prepared from nonionic monomers, preferably used in an amount ranging from 50 to 90 mol%.
    In a particularly preferred manner according to the invention, the flocculation agent is a polymer prepared from acrylamide.
    Also preferably according to the invention, the flocculation agent comprises at least one polymer prepared from at least one anionic monomer chosen from monomers comprising at least one carboxylic acid function; monomer salts comprising at least one carboxylic acid function; monomers comprising at least one sulfonic acid function; monomer salts comprising at least one sulfonic acid function; monomers comprising at least one phosphonic acid function; monomer salts comprising at least one phosphonic acid function. It may be chosen from polymers prepared from anionic monomers, preferably used in an amount ranging from 10 to 50 mol%, preferably from 20 to 40 mol%.
    As examples of anionic monomers chosen for preparing the flocculating agent according to the invention, mention may be made of acrylic acid, methacrylic acid, itaconic acid, crotonic acid, maleic acid and fumaric acid. 2-acrylamido-2-methylpropanesulfonic acid, vinylsulfonic acid, vinylphosphonic acid, allylsulfonic acid, allylphosphonic acid, styrenesulfonic acid and the corresponding water-soluble salts. The water-soluble salts of these anionic monomers are typically salts of an alkali metal, an alkaline earth metal and ammonium. Particularly preferred anionic monomers are acrylic acid, 2-acrylamido-2-methylpropanesulfonic acid and their corresponding salts.
    Also preferably according to the invention, the flocculation agent comprises at least one polymer prepared from at least one cationic monomer chosen from polymers prepared from at least one cationic monomer chosen from diallyldialkyl ammonium salts. ; acidified or quaternized salts of dialkylaminoalkyl acrylates; acidified or quaternized salts of dialkylaminoalkyl methacrylates; acidified or quaternized salts of dialkylaminoalkylacrylamides and acidified or quaternized salts of dialkylaminoalkymethacrylamides. It can be chosen from polymers prepared from cationic monomers, preferably used in an amount ranging from 0.01 to 10 mol%, preferably from 0.1 to 4 mol%. Examples of cationic monomers chosen to prepare the flocculating agent according to the invention include diallyl dimethyl ammonium chloride (DADMAC), dialkylaminoethyl acrylate (ADAME), dialkylaminoethyl methacrylate (MADAME), acrylamido-propyl trimethyl ammonium chloride (APTAC), methacrylamido-propyl trimethyl ammonium chloride (MAPTAC).
    The acidified salts can in particular be obtained by protonation. The quaternized salts can be obtained by reaction with benzyl chloride, methyl chloride (MeCl), aryl chlorides, alkyl or dialkyl sulphates such as dimethyl sulphate.
    According to the invention, the flocculation agent may also comprise at least one polymer prepared from at least one monomer having a hydrophobic character, preferably a monomer chosen from esters of acrylic acid comprising an alkyl or arylalkyl chain. or ethoxylated; esters of methacrylic acid comprising an alkyl, arylalkyl or ethoxylated chain; acrylamide derivatives comprising an alkyl, arylalkyl or dialkyl chain; methacrylamide derivatives comprising an alkyl, arylalkyl or dialkyl chain. When a monomer having a hydrophobic character is used for the preparation of the flocculating agent, its amount may range from 0.001 to 3 mol% relative to the total amount of monomers.
    The polymers used according to the process of the invention as a sulfonated dispersant or as a flocculating agent may be polymers of different shapes. In particular, they may be branched polymers, preferably branched polymers during the polymerization of the monomers used for their preparation. During the polymerization, it is possible to use a branching or crosslinking agent, and optionally a polyfunctional transfer agent. As branching or crosslinking agent, mention may be made of the compounds chosen from methylene-bis-acrylamide (MBA), ethylene glycol diacrylate, polyethylene glycol dimethacrylate, vinyloxyethyl acrylate, vinyloxyethyl methacrylate, triallylamine, glyoxal, the compounds of glycidyl ether type such as ethylene glycol diglycidyl ether, compounds comprising at least one epoxy function, trimercaptotriazine, polyvinyl alcohols, polyvinylamines. The amount of branching or crosslinking agent used is generally less than 4% by weight relative to the amount of monomers.
    The preparation of the sulphonated dispersing agent and the preparation of the flocculating agent can be carried out independently, for example by solution polymerization, gel polymerization, suspension polymerization, micellar polymerization optionally followed by a precipitation step, precipitation polymerization, emulsion polymerization - aqueous or inverted - optionally followed by a spray drying step. Post-hydrolysis or co-hydrolysis of the formed polymer is also possible. Preferably, the polymerization is free radical polymerization, preferably inverse emulsion polymerization or gel polymerization. The free radical polymerization may include free radical polymerization generated by UV, azo, redox or thermal initiators as well as controlled radical polymerization (CRP) techniques or matrix polymerization techniques.
    When added to the aqueous effluent, the sulphonated dispersing agent and the flocculating agent may, independently, be used in liquid form, in solid form, in the form of an emulsion (for example a water-in-oil emulsion) in the form of a suspension, in the form of a powder or in the form of a dispersion in oil. When the solid form is used, the partial or total dissolution in water of the latter can be done using a polymer preparation unit such as Polymer Slicing Unit (PSU) disclosed in EP 2 203 245. Preferably, they are added in the form of an aqueous solution.
    Advantageously, the sulphonated dispersing agent and the flocculating agent may be added to the aqueous effluent during its transport, especially in the effluent transport pipes to deposition sites used for dehydration and solidification. of the treatment residue. The places of deposit can be in the open air. These may be non-delimited lands or closed areas, for example a pond or cell. The treatment steps according to the process of the invention and then spreading of the treated effluent can be renewed in the same place then leading to the superposition of treated residue layers. The spreading can also be carried out continuously to form a cluster of treated residue from which water is extracted. The use of mechanical treatment units may be associated with the process according to the invention. Such mechanical treatment units are in particular devices for centrifugation, pressing or filtration of the treated effluent. A thickener, a centrifuge or a hydrocyclone may be mentioned. The sulphonated dispersing agent and the flocculating agent may be independently added in several portions, in particular alternately or sequentially. Preferably, the dispersant is added at one time. The sulphonated dispersing agent and the flocculating agent may be added in a pipe carrying the effluent to a mechanical treatment unit or in the effluent exiting from such a unit during its transport to a deposition site or to a other mechanical processing unit. The flocculation agent may be added in a pipe conveying the effluent to a deposition zone.
    In addition to the addition to the effluent of at least one sulphonated dispersing agent, then the addition of at least one solid particles flocculation agent, the process according to the invention may also comprise the separation of all or part of the water of the mixture comprising solid particles, the sulfonated dispersing agent and the flocculating agent of these solid particles.
    Preferably during the process according to the invention, the separation of all or part of the water is carried out from the mixture comprising the dispersed solid particles and flocculated.
    The separation of water may, in particular, be carried out by spreading, by centrifugation, by pressing or by filtration. The separation of the water is preferably carried out by spreading.
    In a particularly advantageous manner, the separation of the water makes it possible to eliminate at least 20% by weight of the water included in the effluent. Preferably, it eliminates at least 30% by weight of water included in the effluent. More preferably, it eliminates at least 50% by weight, or even at least 60% by weight, of the water included in the effluent. The quantity of water removed is measured 24 hours after the implementation of the process according to the invention. According to the invention, the measurement of the amount of water removed is carried out by evaluation of the net water release (NWR) of the starting effluent, 24 hours after treatment according to the method.
    According to the process of the invention, it is also possible to measure the moisture content of the final residue (cake) of the process according to the invention once the water has been removed. This measurement is generally carried out 24 hours after the implementation of the method according to the invention.
    According to the invention, the rate of the net water release or the moisture content of the final residue can also be measured after 7 days.
    Preferably according to the invention: the sulphonated dispersing agent has a molecular weight of between 5,000 and 25,000 g / mol, the sulphonated dispersing agent is added in a mass quantity ranging from 500 to 2,000 g per tonne of effluent, and the effluent is a mining effluent, preferably a bituminous sand or oil sand mining effluent comprising from 20 to 50% by weight of solid particles. Also preferably according to the invention: the sulphonated dispersing agent is a co-polymer of 2-acrylamido-2-methylpropanesulfonic acid and at least one nonionic monomer chosen from acrylamide; methacrylamide; N-mono-derivatives of acrylamide; N-mono-derivatives of methacrylamide; Ν, Ν-derivatives of acrylamide; N, N-derivatives of methacrylamide; acrylic esters; methacrylic esters; N-vinylformamide and N-vinylpyrrolidone, the sulphonated dispersing agent has a molecular weight of between 5,000 and 25,000 g / mol, the sulphonated dispersing agent is added in a mass quantity ranging from 500 to 2,000 g per tonne of effluent, and the effluent is a mining effluent, preferably an extraction effluent of bituminous sand or oil sand comprising from 20 to 50% by weight of solid particles.
    In addition to a process, the invention also relates to the use for treating an aqueous effluent comprising solid particles, at least one flocculating agent for solid particles previously dispersed by means of at least one sulphonated dispersing agent. Thus, the invention relates to the use of a flocculation agent for the treatment of an aqueous effluent comprising solid particles and a sulfonated dispersing agent. It also relates to the use of at least one sulphonated dispersing agent and at least one solid particle flocculating agent for treating an aqueous effluent comprising solid particles.
    For the uses according to the invention, the aqueous effluent, the solid particles, the sulphonated dispersing agent and the solid particles flocculation agent are as defined for the process according to the invention. The particular, advantageous or preferred features of the process according to the invention define particular, advantageous and preferred uses according to the invention. The invention also relates to a composition comprising an aqueous effluent comprising solid particles and at least one sulphonated dispersing agent and a composition comprising an aqueous effluent comprising solid particles and dispersed by means of at least one sulphonated dispersing agent. The invention also relates to a composition comprising an aqueous effluent comprising solid particles, at least one sulphonated dispersing agent and at least one flocculation agent and a composition comprising an aqueous effluent comprising solid particles dispersed by means of at least one sulfonated dispersing agent and flocculated by means of at least one flocculation agent.
    Preferably, the composition according to the invention comprises an aqueous effluent comprising solid particles, at least one sulphonated dispersing agent and at least one flocculation agent. Also preferably, the composition according to the invention comprises an aqueous effluent comprising solid particles dispersed by means of at least one sulphonated dispersing agent and the dispersed solid particles of which are flocculated by means of at least one flocculation agent.
    According to the invention, the particular, advantageous or preferred characteristics of the process according to the invention define particular, advantageous or preferred compositions.
    The various aspects of the invention are illustrated by the following examples.
    EXAMPLE 1 Fluidification of an effluent of fine wall type (29.8% by weight of solids) by addition of dispersant
    For each test, the appropriate volume of dispersant solution is added in 200 g of aqueous effluent, then the whole mixture is mixed manually for 30 seconds and the viscosity is measured using a Brookfield viscometer (rotational speed: 3). Rotations per minute).
    Dispersant A = poly (sodium naphthalene sulfonate)
    Dispersant B = polyATBS (homopolymer) at 1500 g / mol Dispersant C = polyATBS at 5000 g / mol Dispersant D = polyATBS at 10,000 g / mol Dispersant E = poly acrylic acid at 2500 g / mol ATBS is tert-butyl sulfonic acid acrylamide.
    The dosages are expressed in g / tonne of aqueous effluent. The results are shown in Table 1.
    Table 1
    These results show that all the dispersants used during the tests make it possible to significantly reduce the viscosity of the effluent.
    EXAMPLE 2 Flocculation of an effluent of fine wall type (29.8% by weight of solids) after addition of dispersant
    For each test, the appropriate volume of flocculant solution is added in 200 g of predispersed residue and then the whole mixture is mixed manually until optimum flocculation and water release is observed. The flocculant used is an anionic polyacrylamide at 30 mol%. The dispersant dosages are expressed in g / tonne of residue. The flocculant dosage for each test is 1100 g / dry ton of effluent. The results are shown in the table.
    Table 2
    Net Water Release (LNE) is the total amount of water recovered during the flocculation test minus the amount of water unduly added during the incorporation of the aqueous polymeric solution and the dispersant solution into the suspension. .
    These results show that the sulfonated dispersants A, B, C and D make it possible to flocculate the residues despite a pre-addition of dispersant. It is also noted that the use of these dispersants leads to better LNE than the treatment consisting in the use of a flocculant alone. It is also noted that the non-sulfonated dispersant E, although effective in fluidizing the effluents, prevents any subsequent flocculation, which makes its use impossible for this application.
    权利要求:
    Claims (14)
    [1" id="c-fr-0001]
    A method of treating an aqueous effluent comprising solid particles, comprising (a) adding to the effluent at least one sulfonated dispersing agent; and then (b) adding at least one solid particle flocculation agent.
    [2" id="c-fr-0002]
    2. Method according to claim 1 for which the effluent is a mining extraction effluent, preferably an extraction effluent of oil sand or oil sand; or an effluent comprising from 5 to 70% by weight, preferably from 20 to 50% by weight, more preferably from 30 to 40% by weight, of solid particles; or an effluent comprising sand, clay and water; or an effluent comprising sand, clay, water and residual bitumen; or an effluent comprising fresh residues; or an effluent comprising fine residues; or an effluent comprising mature fine tailings (RFM or MFT for mature fine tailings); or an effluent comprising mature fine tailings (RFM or MFT) comprising a quantity of clays ranging from 5 to 70% by weight.
    [3" id="c-fr-0003]
    3. Method according to one of claims 1 or 2 wherein the sulfonated dispersing agent is added in an amount by mass ranging from 10 to 10 000 g, preferably from 200 to 5000 g, more preferably 500 and 2000 g per tonne of effluent.
    [4" id="c-fr-0004]
    4. Method according to one of claims 1 to 3 wherein the sulfonated dispersing agent has a molecular weight ranging from 1000 to 50 000 g / mol, preferably from 5000 to 30 000 g / mol, more preferably from 10,000. at 25,000 g / mol; or is selected from 2-acrylamido-2-methylpropanesulfonic acid, vinyl sulfonic acid, styrene sulfonic acid, naphatalenesulphonic acid, allylsulfonic acid homopolymers or co-polymers or soluble salts thereof in water ; or is selected from co-polymers of 2-acrylamido-2-methylpropanesulphonic acid, vinyl sulfonic acid, styrene sulfonic acid, naphatalenesulphonic acid, allylsulfonic acid or their soluble salts in the form of water and o of at least one nonionic monomer, preferably used in an amount ranging from 0.01 to 90 mol%, selected from acrylamide; methacrylamide; N-mono-derivatives of acrylamide; N-mono-derivatives of methacrylamide; Ν, Ν-derivatives of acrylamide; Ν, Ν-derivatives of methacrylamide; acrylic esters; methacrylic esters; N-vinylformamide and N-vinylpyrrolidone.
    [5" id="c-fr-0005]
    5. Method according to one of claims 1 to 4 wherein the flocculating agent is added in an amount ranging from 10 to 10 000 g per ton of solid particles included in the aqueous effluent.
    [6" id="c-fr-0006]
    6. Method according to one of claims 1 to 5 for which the flocculating agent has a molecular weight ranging from 3 to 40 million g / mol, preferably from 5 to 30 million g / mol; or is a polymer prepared from at least one nonionic monomer, preferably used in an amount of from 50 to 90 mol%, selected from acrylamide; methacrylamide; N-mono-derivatives of acrylamide; N-mono-derivatives of methacrylamide; Ν, Ν-derivatives of acrylamide; Ν, Ν-derivatives of methacrylamide; acrylic esters; methacrylic esters; N-vinylformamide and N-vinylpyrrolidone; or comprises at least one polymer prepared from at least one anionic monomer, preferably used in an amount ranging from 10 to 50 mol%, preferably ranging from 20 to 40 mol%, chosen from monomers comprising at least one function carboxylic acid; monomer salts comprising at least one carboxylic acid function; monomers comprising at least one sulfonic acid function; monomers comprising at least one phosphonic acid function; monomer salts comprising at least one phosphonic acid function; or is chosen from polymers prepared from at least one cationic monomer, preferably used in an amount ranging from 0.01 to 10 mol%, preferably from 0.1 to 4 mol%, chosen from the salts diallyldialkyl ammonium; acidified or quaternized salts of dialkylaminoalkyl acrylates; acidified or quaternized salts of dialkylaminoalkyl methacrylates; acidified or quaternized salts of dialkylaminoalkylacrylamides and acidified or quaternized salts of dialkylaminoalkymethacrylamides; or
    [7" id="c-fr-0007]
    7. Method according to one of claims 1 to 6 also comprising the separation of all or part of the water from the mixture of solid particles, sulfonated dispersant and solid particles flocculating agent.
    [8" id="c-fr-0008]
    8. Method according to one of claims 1 to 7 also comprising the separation of all or part of the water from the mixture of dispersed and flocculated solid particles.
    [9" id="c-fr-0009]
    9. Method according to one of claims 7 and 8 for which the separation of water is carried out by spreading, centrifugation, pressing or filtration; or at least 20%, preferably at least 30%, more preferably at least 50%, even more preferably at least 60%, by weight of the water is separated; or the separation of water is measured 24 hours after treatment.
    [10" id="c-fr-0010]
    10. Use for treating an aqueous effluent comprising solid particles, at least one flocculating agent of the solid particles previously dispersed by means of at least one sulfonated dispersing agent.
    [11" id="c-fr-0011]
    11. Use of at least one sulfonated dispersing agent and at least one solid particle flocculating agent for treating an aqueous effluent comprising solid particles.
    [12" id="c-fr-0012]
    12. Use according to one of claims 10 and 11 for which the aqueous effluent, the solid particles, the sulfonated dispersing agent and the solid particles flocculation agent are defined according to claims 1 to 7.
    [13" id="c-fr-0013]
    13. A composition comprising: an aqueous effluent comprising solid particles and at least one sulphonated dispersing agent; or an aqueous effluent comprising solid particles dispersed by means of at least one sulphonated dispersing agent; and at least one flocculation agent; or whose dispersed solid particles are flocculated by means of at least one flocculation agent.
    [14" id="c-fr-0014]
    14. A composition according to claim 13 wherein the aqueous effluent, the solid particles, the sulfonated dispersing agent and the solid particles flocculating agent are defined according to claims 1 to 6.
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    同族专利:
    公开号 | 公开日
    WO2017097799A1|2017-06-15|
    FR3044655B1|2021-06-11|
    US10889512B2|2021-01-12|
    CL2018001502A1|2018-08-17|
    RU2018120175A3|2020-02-26|
    CN108349762A|2018-07-31|
    US20180362371A1|2018-12-20|
    CN108349762B|2021-09-03|
    CA3007272A1|2017-06-15|
    RU2733619C2|2020-10-05|
    RU2018120175A|2019-12-02|
    BR112018011481A2|2018-12-04|
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    法律状态:
    2016-11-29| PLFP| Fee payment|Year of fee payment: 2 |
    2017-06-09| PLSC| Publication of the preliminary search report|Effective date: 20170609 |
    2017-10-19| PLFP| Fee payment|Year of fee payment: 3 |
    2018-09-21| TP| Transmission of property|Owner name: S.P.C.M. SA, FR Effective date: 20180822 |
    2018-10-18| PLFP| Fee payment|Year of fee payment: 4 |
    2019-11-20| PLFP| Fee payment|Year of fee payment: 5 |
    2020-11-18| PLFP| Fee payment|Year of fee payment: 6 |
    2021-11-18| PLFP| Fee payment|Year of fee payment: 7 |
    优先权:
    申请号 | 申请日 | 专利标题
    FR1561918A|FR3044655B1|2015-12-07|2015-12-07|AQUEOUS EFFLUENT TREATMENT PROCESS|FR1561918A| FR3044655B1|2015-12-07|2015-12-07|AQUEOUS EFFLUENT TREATMENT PROCESS|
    RU2018120175A| RU2733619C2|2015-12-07|2016-12-07|Method of treating waste water|
    CA3007272A| CA3007272A1|2015-12-07|2016-12-07|Method for treating aqueous effluent|
    US15/781,960| US10889512B2|2015-12-07|2016-12-07|Method for treating aqueous effluent|
    CN201680061409.1A| CN108349762B|2015-12-07|2016-12-07|Method for treating aqueous effluents|
    BR112018011481-2A| BR112018011481A2|2015-12-07|2016-12-07|method for treating an aqueous effluent, use of at least one agent, use of at least one sulfonated dispersing agent and composition|
    PCT/EP2016/080006| WO2017097799A1|2015-12-07|2016-12-07|Method for treating aqueous effluent|
    CL2018001502A| CL2018001502A1|2015-12-07|2018-06-05|Procedure for the treatment of aqueous effluent.|
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